Tunable aqueous virtual micropore.

نویسندگان

  • Jae Hyun Park
  • Weihua Guan
  • Mark A Reed
  • Predrag S Krstić
چکیده

A charged microparticle can be trapped in an aqueous environment by forming a narrow virtual pore--a cylindrical space region in which the particle motion in the radial direction is limited by forces emerging from dynamical interactions of the particle charge and dipole moment with an external radiofrequency quadrupole electric field. If the particle satisfies the trap stability criteria, its mean motion is reduced exponentially with time due to the viscosity of the aqueous environment; thereafter the long-time motion of particle is subject only to random, Brownian fluctuations, whose magnitude, influenced by the electrophoretic and dielectrophoretic effects and added to the particle size, determines the radius of the virtual pore, which is demonstrated by comparison of computer simulations and experiment. The measured size of the virtual nanopore could be utilized to estimate the charge of a trapped micro-object.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Highly compressed nanosolution restricted in cylindrical carbon nanospaces.

We shed light on the specific hydration structure around a zinc ion of nanosolution restricted in a cylindrical micropore of single-wall carbon nanotube (SWNT) by comparison with the structure restricted in a cylindrical mesopore of multi-wall carbon nanotube (MWNT) and that of bulk aqueous solution. The average micropore width of open-pore SWNT was 0.87 nm which is equivalent to the size of a ...

متن کامل

Optimisation of the conditions for stripping voltammetric analysis at liquid-liquid interfaces supported at micropore arrays: a computational simulation.

Micropore membranes have been used to form arrays of microinterfaces between immiscible electrolyte solutions (µITIES) as a basis for the sensing of non-redox-active ions. Implementation of stripping voltammetry as a sensing method at these arrays of µITIES was applied recently to detect drugs and biomolecules at low concentrations. The present study uses computational simulation to investigate...

متن کامل

Surface-related capacitance of microporous carbons in aqueous and organic electrolytes

This paper examines the surface-related capacitance C/S of carbons with average micropore widths between 0.73 and 1.80 nm, using 1-2M H2SO4, 6M KOH and 1M (C2H5)4NBF4 in acetonitrile as electrolytes. Following corrections for pseudocapacitance effects for the aqueous electrolytes and the use of an average surface area suggested by independent techniques, different from the BET area, it appears ...

متن کامل

Synthesis of polybenzoxazine based nitrogen-rich porous carbons for carbon dioxide capture.

Nitrogen-rich porous carbons (NPCs) were synthesized from 1,5-dihydroxynaphthalene, urea, and formaldehyde based on benzoxazine chemistry by a soft-templating method with KOH chemical activation. They possess high surface areas of 856.8-1257.8 m(2) g(-1), a large pore volume of 0.15-0.65 cm(3) g(-1), tunable pore structure, high nitrogen content (5.21-5.32 wt%), and high char yields. The amount...

متن کامل

The assessment of surface areas in porous carbons by two model - independent techniques , the DR equation and DFT

The strong linear correlation observed between SBET and the micropore volume of 190 carbons with pore widths between 0.5 and 1.8 nm confirms the unreliable character of SBET, in spite of its frequent use. (It corresponds approximately to 2200-2300 m per cm of micropores, whatever their width). Alternative determinations of the surface area are therefore required. It is shown that two model-inde...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Small

دوره 8 6  شماره 

صفحات  -

تاریخ انتشار 2012